Controlled rheology formulations containing high melt strength polypropylene for extrusion coating

ABSTRACT

A process of extruding a blend of an irradiated first propylene polymer and a non-irradiated second propylene polymer, where the first propylene polymer comprises a non-phenolic stabilizer. The irradiation of the first propylene polymer extrudate is conducted in a reduced oxygen environment, and the irradiated first propylene polymer and the non-irradiated second propylene polymer are blended at a temperature below their respective melting points. The blend has a viscosity retention of 20 to 35%.

This continuation application claims benefit of priority under 35 U.S.C.§120 of pending U.S. application Ser. No. 13/024,015, filed Feb. 9,2011, the contents of which are incorporated herein by reference in itsentirety.

FIELD OF THE INVENTION

The present invention relates to a composition for improved extrusionprocesses. More particularly, the present invention relates to a blendof irradiated extrudates of polypropylene and non-irradiatedpolypropylene having particular rheologoical properties for use inextrusion processes.

BACKGROUND OF THE INVENTION

The use of low density polyethylene in extrusion coating onto substratessuch as paper and metal foils has historically been favored over that ofpolypropylene. This is a result of the relative poor extrusion coatingcharacteristics of conventional polypropylenes at high throughput rates,where extension of the polymer melt through the extruder die increases.Conventional polypropylenes don't well-tolerate the higher extension,which adversely affects the orientation of the polymer melt, asevidenced by neck-in, draw resonance, edge weave and poor film quality.

Stabilizing additives are typically added to propylene polymercompositions to protect against degradation due to oxidation involvingheat, UV radiation, ionizing radiation and transition metal impurities.In particular, in extrusion coating, fouling of the die or nip roll dueto degradation products can occur if an appropriate level ofstabilization is not present, potentially resulting in a shutdown of theextrusion coating product line. This is particularly important at higherextrusion temperatures. In addition to unit downtime, degradation canresult in color development, undesirable taste or odor in the resultingpolypropylene. Finally, appropriate stabilization levels are importantto prevent large melt flow shifts at the operating temperature andresidence time of the extruder, and to reduce the sensitivity of theextrusion coating operation to changes in operating conditions, e.g.,extruder temperature, screw rpm, backpressure at the die, etc. Additivesto inhibit degradation include free radical traps, the so-called primaryantioxidants, and peroxide decomposers, sometimes referred to assecondary antioxidants. Hindered phenols and hindered amines are typicalfree-radical traps. Phosphites and thioesters are examples of peroxidedecomposers. Phosphites are effective in the melt phase, and are used toprevent color generation. Thioesters are used for thermal stabilizationto control undesirable taste and odor development in the resultingpolypropylene. They are effective in the solid phase.

Increasing the melt strength of the polypropylene is known to improvemelt orientation. Techniques to improve melt strength in polypropylenehave included irradiation of conventional flake polypropylene inreduced-oxygen environments, as described, for example, in U.S. Pat.Nos. 4,916,198, 5,047,485, 5,414,027, 5,541,236, 5,554,668, 5,591,785,5,731,362, and 5,804,304. For example, U.S. Pat. No. 5,508,318 disclosescompounded blends of irradiated and non-irradiated olefin polymermaterials suitable for extrusion coating applications requiring lowgloss. These irradiation methods increase propylene polymer meltstrength by creating polymer radicals during irradiation which thenre-combine to form long-chain branches in the reduced oxygenenvironment. Conventionally, phenolic antioxidants have long been usedto improve polymer stability under elevated temperature conditions, suchas those typically experienced during extrusion, or during extendedperiods of storage. However, their use in irradiated compositionsundermines enhanced melt strength by scavenging free radicals, therebyreducing the number of polymeric free radicals available to recombine toform long-chain branches. Moreover, irradiation of phenolicantioxidant-containing polymers can result in the formation ofdegradation products that impart undesirable color. Non-phenolicstabilizers have been used in the irradiation of conventional polyolefinmaterials to avoid such problems, as described in U.S. Pat. No.6,664,317. International Publication No. WO 2009/003930 disclosesirradiation of high melt strength polypropylene in the form of pelletscontaining non-phenolic antioxidants. However, a continuing need existsfor extrusion coating processes that provide good film quality at highline speeds.

SUMMARY OF THE INVENTION

The present disclosure relates to a composition made up of a blend of anirradiated first propylene polymer having a non-phenolic stabilizer anda non-irradiated second propylene polymer. The irradiation of the firstpropylene polymer was conducted in a reduced oxygen environment, and theirradiated first propylene polymer and the non-irradiated secondpropylene polymer were blended at a temperature below the melting pointof the first and second propylene polymers, wherein the blend has aviscosity retention (defined below) of 20 to 35%.

In further embodiments, the present disclosure relates to a process ofextruding a blend of an irradiated first propylene polymer and anon-irradiated second propylene polymer, where the first propylenepolymer comprises a non-phenolic stabilizer. The irradiation of thefirst propylene polymer is conducted in a reduced oxygen environment,and the irradiated first propylene polymer and the non-irradiated secondpropylene polymer are blended at a temperature below their respectivemelting points. The blend has a viscosity retention of 20 to 35%.

In other embodiments the present disclosure relates to a process ofblending an irradiated first propylene polymer comprising a non-phenolicstabilizer, and a non-irradiated second propylene polymer, at atemperature below the melting point of the first and second propylenepolymers, thereby forming a polymer blend. The irradiation of the firstpropylene polymer was conducted in a reduced oxygen environment. Theprocess further includes extruding the polymer blend to form a film andcoating the film onto a substrate selected from paper, paperboard,fabrics or metal foils. The polymer blend has a viscosity retention of20 to 35%.

In additional embodiments, the present disclosure relates to a processfor preparing a polymer composition including blending an irradiatedfirst propylene polymer having a non-phenolic stabilizer with anon-irradiated second propylene polymer, wherein the irradiation of thefirst propylene polymer was conducted in a reduced oxygen environment.Further, the irradiated first propylene polymer and the non-irradiatedsecond propylene polymer were blended at a temperature below the meltingpoint of the first and second propylene polymers. The blend has aviscosity retention of 20 to 35%.

DETAILED DESCRIPTION OF THE INVENTION

Propylene Polymer Compositions

The first propylene polymer includes a non-phenolic stabilizer and apropylene polymer selected from:

-   -   (a) a crystalline propylene homopolymer having a xylene        insolubles greater than 80%, preferably greater than 85%,    -   (b) a crystalline random copolymer comprising propylene and an        olefin selected from the group consisting of ethylene and a        C₄-C₁₀ α-olefin, having xylene insolubles greater than 80%,        preferably greater than 82%, with the proviso that when the        α-olefin is ethylene, the crystalline random copolymer comprises        a maximum polymerized ethylene content of about 10% by weight,        and when the α-olefin is a C₄-C₁₀ α-olefin, the crystalline        random copolymer comprises a maximum polymerized α-olefin        content of about 20% by weight,    -   (c) a crystalline random terpolymer comprising propylene and two        olefins selected from the group consisting of ethylene, C₄-C₁₀        α-olefins, and mixtures thereof with the proviso that the        crystalline random terpolymer comprises a maximum polymerized        C₄-C₁₀ α-olefin content of about 20% by weight, and when at        least one of the α-olefins is ethylene, the crystalline random        terpolymer comprises a maximum polymerized ethylene content of        about 5% by weight; and    -   (d) mixtures thereof.

The second propylene polymer is selected from propylene polymers (a)through (d) as described above for the first propylene polymer, and canbe the same or different from the first propylene polymer.

Preferably, the first and second propylene polymers are independentlyselected from a crystalline propylene homopolymer, a crystalline randomcopolymer of propylene and an olefin selected from the group consistingof ethylene and C₄-C₁₀ α-olefins or mixtures thereof. More preferably,the first propylene polymer is a crystalline propylene homopolymer or acrystalline copolymer of propylene and ethylene. Most preferably, thefirst propylene polymer is a crystalline propylene homopolymer.

The first propylene polymer preferably has a melt flow rate of 0.1 to100 dg/min, more preferably 0.15 to 30 dg/min, most preferably 0.2 to 15dg/min. The second propylene polymer preferably has a melt flow rate of0.1 to 100 dg/min, more preferably 0.5 to 50 dg/min, most preferably 1to 35 dg/min. Melt flow rate is determined according to ASTM D 1238,measured at 230° C., 2.16 kg, units of dg/min.

The blend of the irradiated extrudate of the first propylene polymer andthe non-irradiated second propylene polymer preferably contains 5 to 95wt % of the irradiated extrudate of the first propylene polymer and 5 to95 wt % of the non-irradiated second propylene polymer. More preferably,the blend contains 10 to 30 wt % of the irradiated extrudate of thefirst propylene polymer and 70 to 90 wt % of the non-irradiated secondpropylene polymer.

The first and second propylene polymers can be prepared by Ziegler-Nattaor Single-Site (e.g. metallocene) catalysis.

Non-Phenolic Stabilizers

The non-phenolic stabilizers in the first propylene polymer are selectedfrom hindered amines, hydroxylamines, nitrones, amine oxides,benzofuranones, organic phosphites, phosphonites or mixtures thereof.Non-phenolic stabilizers are described in for example, InternationalPublication No. WO 2009/003930. Preferably, the non-phenolic stabilizersare selected from hindered amines, hydroxylamines, phosphites ormixtures thereof. The non phenolic stabilizers are typically present inan amount ranging from about 0.001 to about 1 pph, preferably from about0.005 to about 0.5 pph, and more preferably from about 0.01 to about 0.2pph.

Processes for Producing the Irradiated Polymer Extrudates

The first propylene polymer to be extruded and irradiated according tothe present invention can be produced by a variety of processes, e.g.,by combining the propylene polymer and the non-phenolic stabilizer viamelt blending, blending below their respective melting points (dryblending), or combinations thereof. Preferably, the first propylenepolymer is formed by first dry blending the propylene polymer with thenon-phenolic stabilizer, and then extruding the blended material aboveits melting point. The extrudate produced in the extruder is thensubjected to an irradiation treatment. During irradiation, the extrudatecan be in the form of a solid, semi-solid or melt. Preferably, theextrudate is a solid, more preferably, the extrudate is in the form of apellet. Alternative to extruding, the first propylene polymer may beformed into particles, flakes or other forms by casting or otherprocesses known in the art. However, preferably, the first propylenepolymer is an extrudate.

The first propylene polymer is irradiated in a reduced oxygenenvironment, where the total radiation dosage is preferably about 1 toabout 20 Megarad, more preferably 2 to 15 Megarad, most preferably 3 to12 Megarad. The reduced oxygen environment is maintained duringirradiation to prevent chain-scission reactions.

The expression “active oxygen” throughout this disclosure refers tooxygen in a form that will react with the propylene polymer composition,and more particularly with free radicals present in the propylenepolymer composition, which are produced from the irradiation process.Active oxygen can include, but is not limited to, molecular oxygen,which is the form of oxygen normally found in air.

The expression “reduced oxygen environment” throughout this disclosuremeans an active oxygen concentration less than about 15% by volume,preferably less than 5% by volume, and more preferably less than 0.004%by volume, with respect to a total volume of the reduced oxygenenvironment. Most preferably, the reduced oxygen environment is an inertgas selected from nitrogen, argon, helium and krypton. Typically, thereduced oxygen environment is achieved by replacing part or all of theair in the environment in which the irradiation treatment is conductedby an inert gas, either under vacuum or at positive pressures.

The term “rad” is usually defined as a quantity of ionizing radiationthat results in an absorption of 100 ergs of energy per gram ofirradiated material, regardless of the source of radiation. With regardto the present invention, the amount of energy absorbed by the propylenepolymer composition when it is irradiated usually is not determined.However, the process can be carried out such that the energy absorptionfrom the ionizing radiation can be measured by a conventional dosimeter,which is a measuring device comprising a strip of fabric, film, orcombination thereof, wherein the strip of fabric, film, or combinationthereof comprises a radiation sensitive dye. This radiation-sensitivedye can be used as an energy absorption sensing means. Accordingly, asused throughout this disclosure, the term “rad” means a quantity ofionizing radiation resulting in an absorption of the equivalent of 100ergs of energy per gram of fabric, film, or combination thereofcomprising the radiation sensitive dye of the dosimeter placed at asurface of the propylene polymer composition being irradiated,regardless of the form of the intermediate polyolefin resin at the timeof irradiation.

The radiation from the irradiation treatment can be gamma radiation orelectron beam radiation, with the radiation preferably being electronbeam radiation. Radiation dosage and dosage rates are adjusted to form asubstantial amount of chain scission within the propylene polymercomposition, so as to achieve a desired change in melt strength whileremaining below the gelation point. Typically, the propylene polymercomposition is exposed to the requisite dosage of radiation for a timeperiod ranging from about 0.0001 seconds to several days, the period ofexposure being based on the desired total radiation dose, radiationdosage rate, and the type of radiation being used. Radiation dosagerates are typically about 1 megarad to about 10,000 megarad per minute,preferably about 18 to about 2,000 megarads per minute.

The radiation should have sufficient energy to penetrate, to the extentdesired, the extrudate of the propylene polymer composition, andpreferably to excite the atomic structure of the propylene polymercomposition, but preferably not sufficient energy to affect atomicnuclei within the intermediate polyolefin composition. Typically, theradiation is formed from electrons being beamed from an electrongenerator comprising an accelerating potential of 500-10,000 kilovolts.

After the extrudate of the first propylene polymer has been irradiated,it is maintained in the reduced oxygen environment at temperatures offrom 20° C. to 110° C. for a period of time sufficient for a significantamount of long chain branches to form within the irradiated firstpropylene polymer. A minimum amount of time is needed for sufficientmigration of the propylene resin chain fragments formed by theirradiation to free radical sites, where they can re-form to completechains or otherwise form long branches on the polymer chains.Preferably, the irradiated first propylene polymer is maintained in thereduced oxygen environment after exposure to the radiation for about oneminute to up to about 48 hours, more preferably, for about one minute toabout 24 hours, most preferably 90 minutes to 20 hours.

Following the irradiation treatment, the irradiated extrudate of thefirst propylene polymer can be subjected to a quenching step while it isin the reduced oxygen environment, to deactivate substantially all freeradicals remaining in the irradiated propylene polymer composition. Thequenching step includes raising the temperature of the irradiatedextrudate of the first propylene polymer, while in the reduced oxygenenvironment, to temperatures ranging from about 20° C. to about 200° C.,more preferably from about 100° C. to about 150° C. Conventional freeradical traps, such as methyl mercaptan, can optionally be used duringthe quenching step.

The irradiation step results in an increase in the melt tension of theirradiated first propylene polymer. Preferably, the melt tension of theirradiated extrudate of the first propylene polymer is greater than 0.5cN, preferably greater than 1 cN, more preferably, 3.5 to 40 cN, mostpreferably 20 to 35 cN.

Process for Blending the Irradiated Extrudate and Non-IrradiatedPolymer.

The irradiated extrudate of the first propylene polymer is blended withthe non-irradiated second propylene polymer below the melting points ofboth components. Preferably, the blending is performed at roomtemperature. Blending is conducted in mixing equipment well-known tothose skilled in the art, such as a tumble blender, ribbon blender,henschel blender, or by co-feeding irradiated extrudate throughloss-in-weight (or gravimetric) feeders at the extruder. In this way,suitable dispersion of the high melt strength material into thenon-irradiated material can be obtained without compounding the blendcomponents. Preferably, the blending is conducted by co-feedingirradiated extrudate through loss-in-weight (or gravimetric) feeders atthe extruder.

Additives, Stabilizers, and Fillers

The irradiated extrudate of the first propylene polymer can furthercomprise, in addition to the non-phenolic stabilizer, conventionaladditives and stabilizers well known in the art. In this regard, theirradiated first propylene polymer can additionally comprise at leastone additive, stabilizer, filler, or combination thereof. It will beunderstood by those in the art that additives is a broad term thatencompasses stabilizers and fillers. Additives, stabilizers, and fillerscan include, but are not limited to, UV absorbers, metal deactivators,peroxide scavengers, basic co-stabilizers, acid scavengers, pigments,catalysts, optical brighteners, antistatic agents, and mixtures thereof,which can be added in amounts well known to those skilled in the art.However, any additives, stabilizers, fillers, or the like, added to thefirst propylene polymer should not substantially negatively affect theimproved melt tension of the irradiated first propylene polymerdescribed in the present invention. In particular, the total amount ofany phenolic stabilizers present in the irradiated extrudate of thefirst propylene polymer is at most 500 ppm based on the polymer, morepreferably less than 150 ppm, more preferably less than 100 ppm, andmore preferably less than 50 ppm. Most preferably, the irradiatedextrudate of the first propylene polymer is free of phenolicstabilizers.

The non-irradiated second propylene polymer can comprise conventionalstabilizers and additives well known in the art, in amounts consistentwith maintaining the viscosity retention of the blend of the irradiatedextrudate of the first propylene polymer and the non-irradiated secondpropylene polymer within the desired range. Preferably, thenon-irradiated second propylene polymer contains stabilizers selectedfrom hindered phenols, phospites, thioesters, and mixtures thereof, morepreferably, selected from hindered phenols. The stabilizers arepreferably present in an amount from 0.02 to 0.15 pph, more preferably,from 0.04 to 0.12 pph.

Rheological Properties of Blend

The viscosity of polymer compositions can affect all aspects of theextrusion coating process: line speed, process stability, and filmquality. Such viscosities are dependent not just on the nature of thepolymers in the polymer composition, but also on the temperature of theextrusion coating process. The type and level of polymer stabilizersalso affect the viscosity of the polymer composition, particularly athigh extrusion coating temperatures, since they affect the polymersviscosity as a function of temperature. Polymer systems that performwell at lower extrusion coating temperatures may not perform well athigher temperatures. It has unexpectedly been found that viscosityretention values from 20 to 35%, as defined below, provide improvedextrusion coating performance in terms of film quality and line speed.Preferably, the viscosity retention value is from 22 to 32%. When theviscosity retention is too low, stability problems can be encounteredbecause the process becomes less capable of tolerating changes inoperating conditions. When the viscosity retention is too high,rheological stability problems, such as draw resonance, can beencountered for thin films at high line speed.

Extrusion Coating Process

The extrusion coating process of the invention using the blend of theirradiated extrudate of the first propylene polymer and thenon-irradiated second propylene polymer is preferably conducted at a dietemperature of 550 F to 620 F, more preferably 560 F to 600 F, mostpreferably 575 F to 595 F; a die opening of 20 mils to 35 mils, morepreferably 22 mils to 28 mils; an air gap of 5 inches to 12 inches, morepreferably, 6 inches to 10 inches; and at a coating thickness of 0.3mils to 1.5 mils, more preferably 0.5 mils to 1.0 mils. Line speeds forthe extrusion coating process are preferably 800 feet per minute to 2500feet per minute, more preferably 1200 feet per minute to 2000 feet perminute. The types of rolls used in the extrusion coating process arepreferably textured or polished. More preferably, the type of rolls usedis textured.

Test Methods

Unless otherwise specified, the properties of the polymer materials andcompositions that are set forth in the following examples have beendetermined according to the following test methods:

Viscosity Retention

A polymer composition containing 85 wt % of the non-irradiated propylenepolymer and 15 wt % of the irradiated extrudate of a propylene polymerwere extruded with a Haake 1.25 inch single screw extruder with ⅛″strand die opening at 20 RPM. Two different temperature conditions wereused:

Condition 1: Zone 1=180° C./Zone 2=190° C./Zone 3=190° C./die=190° C.,

Condition 2: Zone 1=280° C./Zone 2=290° C./Zone 3=300° C./die=310° C.

The complex viscosity of the extrudates collected at the two differenttemperatures was measured at 190° C. and 1 rad/sec frequency. Viscosityretention is defined as the complex viscosity ratio of extrudatecondition 2 over extrudate condition 1 times 100 orViscosity Retention=[(η*_(condition 2))/(η*_(condition 1))]×100Melt Flow Rate (“MFR”)

ASTM 131238, measured at 230° C., 2.16 kg, units of dg/min.

Film Quality

Film quality is measured by visually evaluating the films relative tothe following criteria:

-   “Poor:” Film has sand paper texture, non-uniform appearance and    numerous gels.-   “Fair:” Film is smooth, with some areas of non-uniform appearance,    and with some gels present.-   “Good:” Film is smooth, with uniform appearance and few gels.-   “Excellent:” Film is smooth, with uniform appearance and no visual    gels present.    Melt Tension (“MT”)

Melt tension is measured on a Goettfert Rheotens apparatus at 200° C.The Rheoten apparatus consists of two counter-rotating wheels mounted ona balance beam. A melt strand of the polymer is extruded from acapillary die and pulled between the counter-rotating wheels until thestrand ruptures. The pulling velocity of the counter-rotating wheels isinitially constant to establish a baseline of force, with a constantacceleration then applied to the strand until the strand ruptures. Themaximum force measured before rupture during the test is taken as themelt tension. The extensibility of the melt is represented by thevelocity at rupture.

Xylene Insolubles (“XI”)

The weight percent of polymer soluble in xylene at room temperature isdetermined by placing 2.5 g of polymer in 250 ml of xylene at roomtemperature in a vessel equipped with a stirrer, and heating at 135° C.with agitation for 20 minutes to dissolve the whole polymer. Thesolution is cooled to 25° C. while continuing the agitation, and thenleft to stand without agitation for 30 minutes so that the solids cansettle. The solids are filtered with filter paper, the remainingsolution is evaporated by treating it with a nitrogen stream, and thesolid residue is vacuum dried at 80° C. until a constant weight isreached.

Components

The following components are used in the Examples disclosed herewith:

-   -   Pro-fax® 6323 is a non-irradiated polypropylene homopolymer        commercially available from Equistar Chemicals, LP.    -   Pro-fax® 6331 is a non-irradiated polypropylene homopolymer        commercially available from Equistar Chemicals, LP.    -   Irganox 1330 is a sterically hindered phenolic antioxidant        (“3,3′,3′,5,5′,5′-hexa-tert-butyl-a,a′,a′-(mesitylene-2,4,6-triyl)tri-p-cresol”)        commercially available from BASF.    -   Irgafos 168 is a phosphite based stabilizer        (“Tris(2,4-ditert-butylphenyl)phosphate”).    -   Irganox 1010 is a Sterically hindered phenolic antioxidant        (“Pentaerythritol        Tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate)”)        commercially available from BASF.    -   Chimassorb 944 is a hindered amine stabilizer commercially        available from BASF.    -   Irgastab FS042 is a hindered amine stabilizer commercially        available from BASF.    -   Tinuvin 622 is a hindered amine stabilizer commercially        available from BASF.    -   DHT-4A is a stabilizer comprised of Hydrotalcite available from        Kyowa chemical industry.

EXAMPLES

The following examples are illustrative of preferred processes and arenot intended to be limitations thereon. All references to parts,percentages and ratios in this specification refer to percentages byweight of the final composition prepared, and unless otherwiseindicated, all totals equal 100% by weight.

Example 1

An extension-coated film was prepared from a polymer compositioncontaining 85 wt % of a non-irradiated propylene polymer and 15 wt % ofan irradiated extrudate of a propylene polymer. The non-irradiatedpropylene polymer is a propylene homopolymer having an MFR of 20 dg/minand XI of 97.8 wt %, and containing an additive package of 0.07 pph ofIrganox 1330 and 0.05 pph of DHT-4A. The irradiated extrudate wasprepared from a propylene homopolymer having an MFR of 0.14 dg/min andXI of 97.8 wt % compounded with 0.1 pph of Chimassorb 944, and 0.03 pphof calcium stearate, on a JSW extruder to form an extrudate with a meltflow rate of 0.6 dg/min. The extrudate was irradiated in an inertatmosphere, and then thermally treated at 80° C. for 1.5 hours and at140° C. for an additional 1.5 hrs. The melt tension of the irradiatedextrudate was 34 cN and the MFR was 1.7 dg/min.

The polymer composition was formed by dry blending the irradiated andnon-irradiated materials below their melting point in a drum blender.The viscosity retention of the composition was then measured. Thepolymer composition was extrusion-coated onto 4-mil Craft paper using a4.5-inch, 24:1 L/D, 150 horsepower Beloit single screw extruder with acoat hanger type die at a web width of 30 inches. Conditions for theextrusion coating process: air gap, die temperature, roll type, maximumline speed, and coating thickness, as well as the film properties aresummarized in Table 1.

Example 2

An extrusion-coated film was prepared as in Example 1 except that thenon-irradiated propylene polymer is a propylene homopolymer having anMFR of 18 dg/min and XI of 97.8 wt %, and containing an additive packageof 0.08 pph Irganox 168, 0.04 pph of Irgastab FS042, and 0.04 pph ofTinuvin 622, all commercially available from BASF, and 0.05 pph ofcalcium stearate. The viscosity retention of the composition, as well asextrusion conditions and film properties, are summarized in Table 1.

Example 3

An extrusion-coated film was prepared as in Example 1 except that thenon-irradiated propylene polymer is Pro-fax® 6323, a non-irradiatedpropylene homopolymer having an MFR of 12 dg/min, and an XI of 95 wt %and containing 0.056 pph of Irganox 1010, 0.056 pph of Irganox 168, and0.225 pph of distearyl thiodipropionate, commercially available fromReagens USA, Inc. The viscosity retention of the composition, as well asextrusion conditions and film properties, are summarized in Table 1.

Example 4

An extrusion-coated film was prepared as in Example 1 except that thenon-irradiated propylene polymer is Pro-fax® 6331, a non-irradiatedpropylene homopolymer having an MFR of 12 dg/min. and an XI of 95 wt %and containing 0.066 pph of Irganox 1010, 0.06 pph Irganox 168 and 0.05pph calcium stearate. The viscosity retention of the composition, aswell as extrusion conditions and film properties, are summarized inTable 1.

TABLE 1 Comp. Ex. 1 Ex. 2. Ex. 3 Ex. 4 Die opening, 25 25 25 25 milViscosity 22 48 31 31 Retention, % Coating 1 1  1  1 thickness, mil AirGap, inch 6 6  7  7 Die Temp., ° F. 590 590 590  590  Roll type TexturedTextured Textured Textured Film Good Fair Good Good appearance Maxline >1600 <800 2000+  2000+  speed, fpm

All incorporations by reference throughout this disclosure are donewithin the spirit and scope of the disclosure herein, and are not meantto limit the disclosure or scope of the following claims.

Additionally, the present subject matter being thus described, it willbe apparent that the same may be modified or varied in many ways. Suchmodifications and variations are not to be regarded as a departure fromthe spirit and scope of the present subject matter, and all suchmodifications and variations are intended to be included within thescope of the following claims.

We claim:
 1. A composition comprising a blend of an irradiated firstpropylene polymer comprising a non-phenolic stabilizer and anon-irradiated second propylene polymer, wherein the irradiation of thefirst propylene polymer was conducted in the presence of an environmentcontaining more than 0% and less than 15% by volume of oxygen, whereinthe total amount of any phenolic stabilizers present in the firstpropylene polymer is at most 500 ppm, based upon the first propylenepolymer, wherein the irradiated first propylene polymer and thenon-irradiated second propylene polymer were blended at a temperaturebelow the melting point of the first and second propylene polymers, andwherein the blend has a viscosity retention of 20 to 35%.
 2. Thecomposition of claim 1 wherein the first propylene polymer is selectedfrom: (a) a crystalline propylene homopolymer having a xylene insolublesgreater than 80%, (b) a crystalline random copolymer comprisingpropylene and an olefin selected from the group consisting of ethyleneand a C₄-C₁₀ α-olefin, having xylene insolubles greater than 80%, withthe proviso that when the α-olefin is ethylene, the crystalline randomcopolymer comprises a maximum polymerized ethylene content of about 10%by weight, and when the α-olefin is a C₄-C₁₀ α-olefin, the crystallinerandom copolymer comprises a maximum polymerized α-olefin content ofabout 20% by weight, (c) a crystalline random terpolymer comprisingpropylene and two olefins selected from the group consisting ofethylene, C₄-C₁₀ α-olefins, and mixtures thereof with the proviso thatthe crystalline random terpolymer comprises a maximum polymerized C₄-C₁₀α-olefin content of about 20% by weight, and when at least one of theα-olefins is ethylene, the crystalline random terpolymer comprises amaximum polymerized ethylene content of about 5% by weight, and (d)mixtures thereof.
 3. The composition of claim 1 wherein the secondpropylene polymer is selected from crystalline propylene homopolymers,crystalline random copolymers comprising propylene and an olefinselected from ethylene, C₄-C₁₀ α-olefins or mixtures thereof.
 4. Thecomposition of claim 1 wherein the non-phenolic stabilizer is selectedfrom hindered amines, hydroxylamines, phosphites or mixtures thereof. 5.The composition of claim 1 wherein the first propylene polymer is anextrudate.